Noura Dawass

4 80 S URFACE E FFECTS (a) (b) Figure 4.7: (a) Estimation of KBIs in the thermodynamic limit, G 2 (Eqs. (4.1) and (4.2) ) vs. L for the LJ fluid at T = 2 and ρ = 0.4 (dimensionless units), (b) a close-up in of the plots in (a). The values of G 2 are computed for systems with varying number of molecules N . The used RDFs are provided in Figure 4.5.