Noura Dawass

4.3. R ESULTS 4 85 Figure 4.10 Estimation of the surface term in the thermodynamic limit F ∞ 2 (Eq. (4.6) ) as a function of L for the WCA fluid at T = 2 and ρ = 0.6 (dimensionless units). The values of F ∞ 2 are computed for systems with varying number of molecules N . The used RDFs are provided in Figure 4.1. Figure 4.11 Surface effects of finite subvolumes multiplied by the radius of the subvolume LF V (Eq. (4.5) ) as a function of L for the WCA fluid at T = 2 and ρ = 0.6 (dimensionless units). The values of G V are computed for systems with varying number of molecules N . The used RDFs are provided in Figure 4.1.