I. Materials 1,3-Dimethylimidazolium bis(trifluoromethylsulfonyl)imide (99%) was purchased from Iolitec Ionic Liquids Technologies GmbH. Potassium bis(trifluoromethanesulfonyl)imide (97%) and Lithium bis(trifluoromethanesulfonyl)imide (98%) were obtained from Alfa Aesar. Cesium bis(trifluoromethanesulfonyl)imide (98%) was obtained from TCI. Milli-Q water was taken from a Milli-Q Advantage A10 Water Purification System, Millipore (18 M.cm). All chemicals were transferred to a nitrogen-filled MBraun LabMaster glove box via an antechamber that was either evacuated/refilled with nitrogen, or purged with nitrogen gas, and were used without further treatment. Additional details on Materials can be found in Chapters 2 and 5. II. Experimental methods For details on experimental methods please see Chapter 2. III. Computational methods Computational methods used in this Chapter are detailed in Chapter 3. IV. GC analysis and faradaic efficiencies The procedure to analyze gas/liquid products and analyzing faradaic efficiencies are detailed in Chapter 2.
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